Oilfield chemistry

Secondary Mineral Formation Examined During CO₂/Basalt Interaction

This paper presents an experiment investigating dissolution of basaltic primary minerals and conditions favorable for secondary phase formation under deep subsurface storage conditions.

Fig. 1—XRCT images of an unreacted basalt core showing a fine-grained matrix with distributed intergranular and vesicular porosity in axial and transverse views.
Fig. 1—XRCT images of an unreacted basalt core showing a fine-grained matrix with distributed intergranular and vesicular porosity in axial and transverse views.
Source: CCUS 4423733.

Basalt formations are exceptionally reactive CO2-storage candidates because they favor rapid mineral/fluid reactions that promote long-term storage security. Dissolution of basaltic minerals and precipitation of secondary phases alter fluid geochemistry and, potentially, pore structure during CO2 injection and storage. Secondary mineral formation is thought to alter porosity permeability and injectivity, but these effects have not been well-constrained. In this work, a laboratory flow-through experiment designed to quantify dissolution of basaltic primary minerals and conditions favorable for secondary phase formation under deep subsurface storage conditions is presented.

Introduction

Basalt formations have emerged as promising targets for geological CO2 storage because of abundant reactive silicate minerals and the potential to immobilize CO2 through mineral trapping.

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